Zhou, P.; Aschauer, U.; Feurer, T.; Häner, R.; Liu, S. (25 August 2020). A donor-acceptor ensemble: merging of TTF and dipyrrolylquinoxaline difluoroborate chemistry (Unpublished). In: SCS Fall Meeting 2020.
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Tetrathiafulvalene(TTF)-fused donor-acceptor (D–A) ensembles are of high interest due to their unique (opto)electronic properties and potential applications in organic conductors, photovoltaics, sensors, switches and molecular electronics. A direct annulation of a TTF with a variety of electron-acceptors has been achieved for studying photo-induced intramolecular charge transfer (ICT) as well as the photogeneration of long-lived charge separated states in resultant D-A systems. Herein, we describe redox and optical properties of a new D–A ensemble (Chart 1) which was prepared by complexation of BF2 with a TTF-fused 2,3-di(1H-2-pyrrolyl)quinoxaline ligand. A detailed experimental and theoretical study of an ICT process in TTF-QB is presented.
Item Type: |
Conference or Workshop Item (Poster) |
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Division/Institute: |
08 Faculty of Science > Institute of Applied Physics 08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Zhou, Ping, Aschauer, Ulrich Johannes, Feurer, Thomas, Häner, Robert, Liu, Shi-Xia |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
Language: |
English |
Submitter: |
Ping Zhou |
Date Deposited: |
07 Apr 2021 10:16 |
Last Modified: |
05 Dec 2022 15:49 |
BORIS DOI: |
10.48350/153742 |
URI: |
https://boris.unibe.ch/id/eprint/153742 |
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