A Versatile Broadband Attached Proton Test Experiment for Routine 13C Nuclear Magnetic Resonance Spectroscopy.

Bigler, Peter; Gjuroski, Ilche; Chakif, Dib; Furrer, Julien (2024). A Versatile Broadband Attached Proton Test Experiment for Routine 13C Nuclear Magnetic Resonance Spectroscopy. Molecules, 29(4) MDPI 10.3390/molecules29040809

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The proposed broadband attached proton test sequence allows the user to easily record 13C nuclear magnetic resonance multiplicity-edited and quaternary-carbon-only spectra. Compared to earlier attached proton test experiments, it preserves both a tolerance for wide ranges of one-bond-coupling constant values and the effective suppression of residual CHn signals in the quaternary-carbon-only spectra. The recording of edited spectra or quaternary-carbon-only spectra is made easy by a single, user-controllable constant. These attributes make the broadband attached proton test experiment attractive for the 13C analysis of small molecules, including spectral editing, particularly in high-throughput analysis laboratories.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP)

UniBE Contributor:

Bigler, Peter, Gjuroski, Ilche, Chakif, Dib, Furrer, Julien

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry
000 Computer science, knowledge & systems

ISSN:

1420-3049

Publisher:

MDPI

Language:

English

Submitter:

Pubmed Import

Date Deposited:

27 Feb 2024 13:14

Last Modified:

07 Aug 2024 15:44

Publisher DOI:

10.3390/molecules29040809

PubMed ID:

38398560

Uncontrolled Keywords:

13C 1H 1JCH-tolerance APT Cq-only NMR broadband APT

BORIS DOI:

10.48350/193229

URI:

https://boris.unibe.ch/id/eprint/193229

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