Time-resolved Spectroelectrochemical Investigation of Organic Mixed Conductors.

Cavassin, Priscila; Banerji, Natalie (2024). Time-resolved Spectroelectrochemical Investigation of Organic Mixed Conductors. CHIMIA, 78(4), pp. 192-195. Schweizerische Chemische Gesellschaft 10.2533/chimia.2024.192

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Organic mixed ionic and electronic conductors (OMIECs) are an emerging class of materials that have been applied for a wide range of electrochemical applications. Due to the complexity inherent to the ionic-electroniccoupling, understanding the underlying mechanisms involved in the OMIEC operation is an exciting and very lively research field. In this work, we highlight the use of time-resolved Vis-NIR spectroelectrochemistry tocharacterize these materials. We discuss an example, where we show that by combining this tool with spectraldecomposition, we are able to understand fundamental aspects of the doping in an OMIEC film. The methodswe present here can be generalized and used to characterize any electrochromic material.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP)

UniBE Contributor:

Cavassin, Priscila, Banerji, Natalie

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

0009-4293

Publisher:

Schweizerische Chemische Gesellschaft

Language:

English

Submitter:

Pubmed Import

Date Deposited:

30 Apr 2024 16:19

Last Modified:

01 May 2024 04:20

Publisher DOI:

10.2533/chimia.2024.192

PubMed ID:

38676607

Uncontrolled Keywords:

Conjugated polymers Electrochemical doping OMIECs Spectroelectrochemistry

BORIS DOI:

10.48350/196324

URI:

https://boris.unibe.ch/id/eprint/196324

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