Simona, F.; Hai, N.T.M.; Broekmann, P.; Cascella, M. (2011). From Structure to Function: Characterization of Cu(I) Adducts in Leveler Additives by DFT Calculations. The journal of physical chemistry letters, 2(24), pp. 3081-3084. Washington, D.C.: American Chemical Society 10.1021/jz201430h
Full text not available from this repository.We present the first molecular model of the coordination complex formed by Cu(I) and imidazole-epichlorohydrin polymers. Our calculations show that the Cu(I) ion has linear coordination and the whole complex has neutral charge. Our model suggests salt couple pairing as the driving force for the formation of the surface-confined precipitation, which is crucial to obtain flat surfaces in industrial copper deposition processes, required for mass fabrication of state-of-the-art electronic and memory devices.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Broekmann, Peter, Cascella, Michele |
ISSN: |
1948-7185 |
Publisher: |
American Chemical Society |
Language: |
English |
Submitter: |
Factscience Import |
Date Deposited: |
04 Oct 2013 14:26 |
Last Modified: |
05 Dec 2022 14:07 |
Publisher DOI: |
10.1021/jz201430h |
Web of Science ID: |
000298215000015 |
URI: |
https://boris.unibe.ch/id/eprint/9189 (FactScience: 214871) |
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