Thermal and near-infrared light induced spin crossover in a mononuclear iron( ii ) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

Pointillart, F.; Liu, X.; Kepenekian, M.; Le Guennic, B.; Golhen, S.; Dorcet, V.; Roisnel, T.; Cador, O.; You, Z.; Hauser, Jürg; Decurtins, Silvio; Ouahab, L.; Liu, Shi-Xia (2016). Thermal and near-infrared light induced spin crossover in a mononuclear iron( ii ) complex with a tetrathiafulvalene-fused dipyridophenazine ligand. Dalton transactions, 45(28), pp. 11267-11271. Royal Society of Chemistry 10.1039/C6DT00920D

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A mononuclear Fe(II) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.

Item Type:

Journal Article (Original Article)

Division/Institute:

08 Faculty of Science > Departement of Chemistry and Biochemistry

UniBE Contributor:

Hauser, Jürg; Decurtins, Silvio and Liu, Shi-Xia

Subjects:

500 Science > 570 Life sciences; biology
500 Science > 540 Chemistry

ISSN:

1477-9226

Publisher:

Royal Society of Chemistry

Language:

English

Submitter:

Silvio Decurtins

Date Deposited:

22 Jul 2016 13:43

Last Modified:

19 Jan 2017 16:19

Publisher DOI:

10.1039/C6DT00920D

BORIS DOI:

10.7892/boris.84403

URI:

https://boris.unibe.ch/id/eprint/84403

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