Pointillart, F.; Liu, X.; Kepenekian, M.; Le Guennic, B.; Golhen, S.; Dorcet, V.; Roisnel, T.; Cador, O.; You, Z.; Hauser, Jürg; Decurtins, Silvio; Ouahab, L.; Liu, Shi-Xia (2016). Thermal and near-infrared light induced spin crossover in a mononuclear iron( ii ) complex with a tetrathiafulvalene-fused dipyridophenazine ligand. Dalton transactions, 45(28), pp. 11267-11271. Royal Society of Chemistry 10.1039/C6DT00920D
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A mononuclear Fe(II) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.
Item Type: |
Journal Article (Original Article) |
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Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) |
UniBE Contributor: |
Hauser, Jürg, Decurtins, Silvio, Liu, Shi-Xia |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry |
ISSN: |
1477-9226 |
Publisher: |
Royal Society of Chemistry |
Language: |
English |
Submitter: |
Silvio Decurtins |
Date Deposited: |
22 Jul 2016 13:43 |
Last Modified: |
05 Dec 2022 14:57 |
Publisher DOI: |
10.1039/C6DT00920D |
BORIS DOI: |
10.7892/boris.84403 |
URI: |
https://boris.unibe.ch/id/eprint/84403 |
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