Bösch, Caroline D.; Abay, Elif; Langenegger, Simon M.; Nazari, Maryam; Cannizzo, Andrea; Feurer, Thomas; Häner, Robert (2019). DNA‐Organized Light‐Harvesting Antennae: Energy Transfer in Polyaromatic Stacks Proceeds through Interposed Nucleobase Pairs. Helvetica chimica acta, 102(8) Wiley 10.1002/hlca.201900148
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B-sch_et_al-2019-Helvetica_Chimica_Acta.pdf - Published Version Restricted to registered users only Available under License Publisher holds Copyright. Download (6MB) |
DNA-based light-harvesting antennae with varying arrangements of light-absorbing phenanthrene donor units and a pyrene acceptor dye were synthesized and tested for their light-harvesting properties. Excitation of phenanthrene is followed by rapid transfer of the excitation energy to the pyrene chromophore. A block of six light-absorbing phenanthrenes was separated from the site of the acceptor in a stepwise manner by an increasing number of intervening AT base pairs. Energy transfer occurs via interposed AT base pairs and is still detected when the phenanthrene antenna is separated by 5 AT base pairs.
Item Type: |
Journal Article (Original Article) |
|---|---|
Division/Institute: |
08 Faculty of Science > Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP) 08 Faculty of Science > Institute of Applied Physics 08 Faculty of Science > Institute of Applied Physics > NCCR MUST |
UniBE Contributor: |
Langenegger, Simon Matthias, Nazari Haghighi Pashaki, Maryam, Cannizzo, Andrea, Feurer, Thomas, Häner, Robert |
Subjects: |
500 Science > 570 Life sciences; biology 500 Science > 540 Chemistry 600 Technology > 620 Engineering 500 Science > 530 Physics |
ISSN: |
0018-019X |
Publisher: |
Wiley |
Funders: |
[4] Swiss National Science Foundation |
Language: |
English |
Submitter: |
Robert Häner |
Date Deposited: |
07 Aug 2019 08:47 |
Last Modified: |
05 Dec 2022 15:30 |
Publisher DOI: |
10.1002/hlca.201900148 |
BORIS DOI: |
10.7892/boris.132378 |
URI: |
https://boris.unibe.ch/id/eprint/132378 |
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