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Logallo, Alessandra; Maddock, Lewis C H; Mu, Manting; Gravolg, Lisa; Jin, Na; Peñas Defrutos, Marconi; Meyer, Karsten; Garcia-Melchor, Max; Hevia, Eva (2024). Unlocking the Metalation Applications of TMP-powered Fe and Co(II) Bis(amides): Synthesis, Structure and Mechanistic Insights. Angewandte Chemie. International edition, 63(24), e202402907. Wiley 10.1002/anie.202402907
Dankert, Fabian; Hevia, Eva (2024). Synthesis and Modular Reactivity of Low Valent Al/Zn Heterobimetallics Supported by Common Monodentate Amides. Chemistry: a European journal, 30(16), e202304336. Wiley 10.1002/chem.202304336
Judge, Neil R.; Logallo, Alessandra; Hevia, Eva (2023). Main group metal-mediated strategies for C–H and C–F bond activation and functionalisation of fluoroarenes. Chemical Science, 14(42), pp. 11617-11628. Royal Society of Chemistry 10.1039/D3SC03548D
Liang, Haosheng; Borys, Andryj M.; Hevia, Eva; Perrin, Marie-Eve L.; Payard, Pierre-Adrien (2023). Shedding Light on the Hidden Roles of Lithium in the Nickel-Catalyzed Cross-Coupling of Aryl Ethers. Journal of the American Chemical Society, 145(36), pp. 19989-19999. ACS Publications 10.1021/jacs.3c06647
Mu, Manting; Logallo, Alessandra; Hevia, Eva; García‐Melchor, Max (2023). Interaction and Energy Decomposition Analyses to Predict Stability of Tetraaryl Square Planar Cobalt Complexes. ChemCatChem, 15(19) WILEY-VCH 10.1002/cctc.202300769
Tortajada, Andreu; Hevia, Eva (2023). Alkali-metal bases in catalytic hydrogen isotope exchange processes. Catalysis science & technology, 13(17), pp. 4919-4925. Royal Society of Chemistry 10.1039/d3cy00825h
Judge, Neil; Hevia, Eva (2023). Alkali-Metal-Alkoxide Powered Zincation of Fluoroarenes Employing Zinc Bis-Amide Zn(TMP)2. Angewandte Chemie. International edition, 62(29), e202303099. Wiley 10.1002/anie.202303099
Tortajada, Andreu; Bole, Leonie J.; Mu, Manting; Stanford, Martin; Peñas-Defrutos, Marconi N.; García-Melchor, Max; Hevia, Eva (2023). Sodium mediated deprotonative borylation of arenes using sterically demanding B(CH 2 SiMe 3 ) 3 : unlocking polybasic behaviour and competing lateral borane sodiation. Chemical Science, 14(24), pp. 6538-6545. Royal Society of Chemistry 10.1039/D3SC01705B
Borys, Andryj M.; Hevia, Eva (2023). Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters. Chemical communications, 59(46), pp. 7032-7035. Royal Society of Chemistry 10.1039/D3CC01729J
Tortajada, Andreu; Hevia, Eva (2023). Uncovering the Untapped Potential of the Use of Sodium Amides for Regioselective Arene Functionalisation. CHIMIA, 77(4), p. 225. Schweizerische Chemische Gesellschaft 10.2533/chimia.2023.225
Logallo, Alessandra; Hevia, Eva (2023). Applying Na/Co( ii ) bimetallic partnerships to promote multiple Co–H exchanges in polyfluoroarenes. Chemical communications, 59(36), pp. 5383-5386. Royal Society of Chemistry 10.1039/D3CC01216F
Borys, Andryj M.; Kunzmann, Tim; Gil Negrete, Jose M.; Hevia, Eva (2023). Atom-efficient arylation of N-tosylimines mediated by cooperative ZnAr2/Zn(C6F5)2 combinations. Chemical communications, 59(49), pp. 7583-7586. Royal Society of Chemistry 10.1039/D3CC01490H
Mastropierro, Pasquale; Platten, Andrew W. J.; Kennedy, Alan R.; Hevia, Eva; Uzelac, Marina (2023). Structural and Synthetic Insights on Oxidative Homocouplings of Alkynes Mediated by Alkali‐Metal Manganates. Chemistry - a European journal, 29(33), e202300593. Wiley-VCH 10.1002/chem.202300593
Anderson, David; Tortajada, Andreu; Hevia, Eva (2023). Highly Reactive Hydrocarbon Soluble Alkylsodium Reagents for Benzylic Aroylation of Toluenes using Weinreb Amides. Angewandte Chemie. International edition, 62(11), e202218498. Wiley 10.1002/anie.202218498
Tortajada, Andreu; Hevia, Eva (2023). Stable organolithium gels. Nature chemistry, 15(3), pp. 299-300. Springer Nature 10.1038/s41557-023-01143-y
Borys, Andryj M.; Dell'Aera, Marzia; Capriati, Vito; Hevia, Eva (2023). Structural and synthetic insights into the chemistry of lithium tetraorganozincates. Advances in organometallic chemistry, 80, pp. 1-38. Elsevier 10.1016/bs.adomc.2022.11.001
Borys, Andryj M.; Hevia, Eva (2023). New Frontiers in Alkali-Metal Nickelates. CHIMIA, 77(4), pp. 242-245. Swiss Chemical Society 10.2533/chimia.2023.242
Borys, Andryj M.; Hevia, Eva (2023). Diphenylacetylene stabilised alkali-metal nickelates: synthesis, structure and catalytic applications. Dalton transactions, 52(7), pp. 2098-2105. Royal Society of Chemistry 10.1039/D3DT00069A
Mulks, Florian F.; Pinho, Bruno; Platten, Andrew W.; Andalibi, M. Reza; Expósito, Antonio J.; Edler, Karen J.; Hevia, Eva; Torrente-Murciano, Laura (2022). Continuous, stable, and safe organometallic reactions in flow at room temperature assisted by deep eutectic solvents. Chem, 8(12), pp. 3382-3394. Elsevier 10.1016/j.chempr.2022.11.004
Tortajada, Andreu; Hevia, Eva (2022). Perdeuteration of Arenes via Hydrogen Isotope Exchange Catalyzed by the Superbasic Sodium Amide Donor Species NaTMP·PMDETA. Journal of the American Chemical Society, 144(44), pp. 20237-20242. American Chemical Society 10.1021/jacs.2c09778
Logallo, Alessandra; Mu, Manting; García‐Melchor, Max; Hevia, Eva (2022). Building Square Planar Cobalt (II) Complexes via Sodium Mediated Cobaltation of Fluoroarenes. Angewandte Chemie (International ed.), 61(49), e202213246. Wiley-VCH 10.1002/anie.202213246
Kremsmair, Alexander; Sunagatullina, Alisa S.; Bole, Leonie J; Mastropierro, Pasquale; Graßl, Simon; Wilke, Henrik R.; Godineau, Edouard; Hevia, Eva; Knochel, Paul (2022). Exploiting Coordination Effects for the Regioselective Zincation of Diazines Using TMPZnX⋅LiX (X=Cl, Br). Angewandte Chemie International Edition, 61(40), e202210491. GDCh 10.1002/anie.202210491
Ballmann, Gerd M.; Gentner, Thomas X.; Kennedy, Alan R.; Hevia, Eva; Mulvey, Robert E. (2022). Heavy Alkali Metal Manganate Complexes: Synthesis, Structures and Solvent‐Induced Dissociation Effects. Chemistry – A European Journal, 28(55), e202201716. European Chemical Societies Publishing 10.1002/chem.202201716
Tortajada, Andreu; Anderson, David E; Hevia, Eva (2022). Gram‐Scale Synthesis, Isolation and Characterisation of Sodium Organometallics: n BuNa and NaTMP. Helvetica chimica acta, 105(8) Verlag Helvetica Chimica Acta 10.1002/hlca.202200060
Logallo, Alessandra; Hevia, Eva (2022). Alkali Metal Metal(ates) Containing Divalent Earth Abundant Transition Metals. CHIMIA, 76(4), pp. 336-340. Schweizerische Chemische Gesellschaft 10.2533/chimia.2022.336
Bole, Leonie J; Tortajada, Andreu; Hevia, Eva (2022). Enhancing Metalating Efficiency of the Sodium Amide NaTMP in Arene Borylation Applications. Angewandte Chemie International Edition, 61(26), e202204262. CDCh 10.1002/anie.202204262
Bole, Leonie J.; Hevia, Eva (2022). Activation of polar organometallic reagents with alkali-metal alkoxides. Nature Synthesis, 1(3), pp. 195-202. Springer Nature 10.1038/s44160-022-00040-5
Mastropierro, Pasquale; Kennedy, Alan R.; Hevia, Eva (2022). Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand. Chemical Communications, 58(34), pp. 5292-5295. Royal Society of Chemistry 10.1039/D2CC00979J
Borys, Andryj M.; Hevia, Eva (2022). Mechanisms of the Nickel-Catalysed Hydrogenolysis and Cross-Coupling of Aryl Ethers. Synthesis - journal of synthetic organic chemistry, 54(13), pp. 2976-2990. Thieme 10.1055/a-1806-4513
Judge, Neil R.; Bole, Leonie J.; Hevia, Eva (2022). Assessing Alkali-Metal Effects in the Structures and Reactivity of Mixed-Ligand Alkyl/Alkoxide Alkali-Metal Magnesiates. Chemistry - a European journal, 28(10), e202104164. Wiley-VCH 10.1002/chem.202104164
Somerville, Rosie J.; Borys, Andryj M.; Perez-Jimenez, Marina; Nova, Ainara; Balcells, David; Malaspina, Lorraine A.; Grabowsky, Simon; Carmona, Ernesto; Hevia, Eva; Campos, Jesús (2022). Unmasking the constitution and bonding of the proposed lithium nickelate “Li 3 NiPh 3 (solv) 3 ”: revealing the hidden C 6 H 4 ligand. Chemical Science, 13(18), pp. 5268-5276. The Royal Society of Chemistry 10.1039/d2sc01244h
Platten, Andrew W. J.; Borys, Andryj M.; Hevia, Eva (2021). Hydrophosphinylation of Styrenes Catalysed by Well‐Defined s‐Block Bimetallics. ChemCatChem, 14(5) WILEY-VCH 10.1002/cctc.202101853
De Tullio, Marco; Borys, Andryj M.; Hernán-Gómez, Alberto; Kennedy, Alan R.; Hevia, Eva (2021). Regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles catalyzed by cooperative s-block bimetallics. Chem Catalysis, 1(6), pp. 1308-1321. Elsevier 10.1016/j.checat.2021.09.016
Maddock, Lewis C. H.; Kennedy, Alan R.; Hevia, Eva (2021). Structural and Synthetic Insights into Sodium‐Mediated‐Ferration of Fluoroarenes. Helvetica chimica acta, 104(12) Verlag Helvetica Chimica Acta 10.1002/hlca.202100206
Desaintjean, Alexandre; Haupt, Tobias; Bole, Leonie J.; Judge, Neil R.; Hevia, Eva; Knochel, Paul (2021). Regioselective Bromine/Magnesium Exchange for the Selective Functionalization of Polyhalogenated Arenes and Heterocycles. Angewandte Chemie (International ed.), 60(3), pp. 1513-1518. Wiley-VCH 10.1002/anie.202012496
Borys, Andryj M.; Hevia, Eva (2021). Exploiting chemical cooperativity in main-group bimetallic catalysis. Trends in chemistry, 3(10), pp. 803-806. Elsevier 10.1016/j.trechm.2021.07.006
Bole, Leonie J.; Uzelac, Marina; Hernán-Gómez, Alberto; Kennedy, Alan R.; O’Hara, Charles T.; Hevia, Eva (2021). Progressing the Frustrated Lewis Pair Abilities of N-Heterocyclic Carbene/GaR 3 Combinations for Catalytic Hydroboration of Aldehydes and Ketones. Inorganic chemistry, 60(18), pp. 13784-13796. American Chemical Society 10.1021/acs.inorgchem.1c01276
Borys, Andryj M.; Hevia, Eva (2021). The Anionic Pathway in the Nickel‐Catalysed Cross‐Coupling of Aryl Ethers. Angewandte Chemie (International ed.), 60(46), pp. 24659-24667. Wiley-VCH 10.1002/anie.202110785
Borys, Andryj M.; Gil-Negrete, Jose M.; Hevia, Eva (2021). Atom-efficient transition-metal-free arylation of N , O -acetals using diarylzinc reagents through Zn/Zn cooperativity. Chemical communications, 57(71), pp. 8905-8908. Royal Society of Chemistry 10.1039/D1CC04137A
Maddock, Lewis C. H.; Morton, Rebekka; Kennedy, Alan R.; Hevia, Eva (2021). Lateral Metallation and Redistribution Reactions of Sodium Ferrates Containing Bulky 2,6‐Diisopropyl‐ N ‐(trimethylsilyl)anilide Ligands. Chemistry - a European journal, 27(61), pp. 15181-15187. Wiley-VCH 10.1002/chem.202102328
García‐Garrido, Sergio E.; Presa Soto, Alejandro; Hevia, Eva; García‐Álvarez, Joaquín (2021). Advancing Air‐ and Moisture‐Compatible s‐Block Organometallic Chemistry Using Sustainable Solvents. European journal of inorganic chemistry, 2021(31), pp. 3116-3130. Wiley-VCH 10.1002/ejic.202100347
Maddock, Lewis C. H.; Mu, Manting; Kennedy, Alan R.; García‐Melchor, Max; Hevia, Eva (2021). Facilitating the Ferration of Aromatic Substrates through Intramolecular Sodium Mediation. Angewandte Chemie (International ed.), 60(28), pp. 15296-15301. Wiley-VCH 10.1002/anie.202104275
Mastropierro, Pasquale; Kennedy, Alan R.; Hevia, Eva (2021). Exploiting Deprotonative Co‐complexation to Access Potassium Metal(ates) Supported by a Bulky Silyl(bis)amide Ligand. European journal of inorganic chemistry, 2021(11), pp. 1016-1022. Wiley-VCH 10.1002/ejic.202001051
Gentner, Thomas X.; Kennedy, Alan R.; Hevia, Eva; Mulvey, Robert E. (2021). Alkali Metal (Li, Na, K, Rb, Cs) Mediation in Magnesium Hexamethyldisilazide [Mg(HMDS) 2 ] Catalysed Transfer Hydrogenation of Alkenes. ChemCatChem, 13(10), pp. 2371-2378. WILEY-VCH 10.1002/cctc.202100218
Uzelac, Marina; Mastropierro, Pasquale; Tullio, Marco; Borilovic, Ivana; Tarrés, Màrius; Kennedy, Alan R.; Aromí, Guillem; Hevia, Eva (2021). Tandem Mn–I Exchange and Homocoupling Processes Mediated by a Synergistically Operative Lithium Manganate. Angewandte Chemie (International ed.), 60(6), pp. 3247-3253. Wiley-VCH 10.1002/anie.202013153
Borys, Andryj M.; Hevia, Eva (2021). Beyond Ni{N(SiMe 3 ) 2 } 2 : Synthesis of a Stable Solvated Sodium Tris-Amido Nickelate. Organometallics, 40(3), pp. 442-447. American Chemical Society 10.1021/acs.organomet.0c00785
Bole, Leonie J.; Judge, Neil R.; Hevia, Eva (2021). Untangling the Complexity of Mixed Lithium/Magnesium Alkyl/Alkoxy Combinations Utilised in Bromine/Magnesium Exchange Reactions. Angewandte Chemie (International ed.), 60(14), pp. 7626-7631. Wiley-VCH 10.1002/anie.202016422
Gil-Negrete, Josep M.; Hevia, Eva (2021). Main group bimetallic partnerships for cooperative catalysis. Chemical Science, 12(6), pp. 1982-1992. The Royal Society of Chemistry 10.1039/D0SC05116K
Maddock, Lewis C. H.; Kennedy, Alan; Hevia, Eva (2020). Lithium-mediated Ferration of Fluoroarenes. CHIMIA, 74(11), pp. 866-870. Schweizerische Chemische Gesellschaft 10.2533/chimia.2020.866
Mulks, Florian F.; Bole, Leonie J.; Davin, Laia; Hernán‐Gómez, Alberto; Kennedy, Alan; García‐Álvarez, Joaquín; Hevia, Eva (2020). Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali‐Metal Amides under Air. Angewandte Chemie (International ed.), 59(43), pp. 19021-19026. Wiley-VCH 10.1002/anie.202008512
Hevia, Eva (2020). Towards a Paradigm Shift in Polar Organometallic Chemistry. CHIMIA, 74(9), pp. 681-688. Schweizerische Chemische Gesellschaft 10.2533/chimia.2020.681
Mastropierro, Pasquale; Livingstone, Zoe; Robertson, Stuart D.; Kennedy, Alan R.; Hevia, Eva (2020). Structurally Mapping Alkyl and Amide Basicity in Zincate Chemistry: Diversity in the Synthesis of Mixed Sodium–Zinc Complexes and Their Applications in Enolate Formation. Organometallics, 39(23), pp. 4273-4281. American Chemical Society 10.1021/acs.organomet.0c00339
Elorriaga, David; Rodríguez-Álvarez, María Jesús; Ríos-Lombardía, Nicolás; Morís, Francisco; Presa Soto, Alejandro; González-Sabín, Javier; Hevia, Eva; García-Álvarez, Joaquín (2020). Combination of organocatalytic oxidation of alcohols and organolithium chemistry (RLi) in aqueous media, at room temperature and under aerobic conditions. Chemical communications, 56(63), pp. 8932-8935. Royal Society of Chemistry 10.1039/D0CC03768K
Fairley, Michael; Bole, Leonie J.; Mulks, Florian F.; Main, Laura; Kennedy, Alan R.; O'Hara, Charles T.; García-Alvarez, Joaquín; Hevia, Eva (2020). Ultrafast Amidation of Esters using Lithium Amides under Aerobic Ambient Temperature Conditions in Sustainable Solvents. Chemical Science, 11(25), pp. 6500-6509. The Royal Society of Chemistry 10.1039/D0SC01349H
Honeyman, Gordon W.; Armstrong, David R.; Clegg, William; Hevia, Eva; Kennedy, Alan R.; McLellan, Ross; Orr, Samantha A.; Parkinson, John A.; Ramsay, Donna L.; Robertson, Stuart D.; Towie, Stephen; Mulvey, Robert E. (2020). A regioselectively 1,1′,3,3′-tetrazincated ferrocene complex displaying core and peripheral reactivity. Chemical Science, 11(25), pp. 6510-6520. Royal Society of Chemistry 10.1039/D0SC01612H
Dell'Aera, Marzia; Perna, Filippo Maria; Vitale, Paola; Altomare, Angela; Palmieri, Alessandro; Maddock, Lewis C. H.; Bole, Leonie J.; Kennedy, Alan R.; Hevia, Eva; Capriati, Vito (2020). Boosting Conjugate Addition to Nitroolefins Using Lithium Tetraorganozincates: Synthetic Strategies and Structural Insights. Chemistry - a European journal, 26(40), pp. 8742-8748. Wiley-VCH 10.1002/chem.202001294
